The most important thing you can do to prevent chocolate from seizing is to eliminate any chance of the chocolate coming into contact with water.
Always make sure the bowls and utensils you are using are perfectly dry. Avoid using wooden spoons or boards, as they might retain moisture and impart this moisture to your chocolate.
If you are using a double boiler to melt your chocolate, keep the water hot but not boiling, or turn off the heat before the chocolate is placed on top. Boiling water might splash above the rim of the saucepan and cause droplets to fall in the chocolate.
In addition, boiling water gives off a great deal of steam, and steam can also cause chocolate to seize. Be sure to wipe the bottom of the bowl the chocolate is melting in on a regular basis, to remove water and condensation.
Finally, never cover warm chocolate with a lid, as the heat of the chocolate might form condensation on the inside of the bowl, which will cause the chocolate to seize.
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